China Crms Manufacturers –  Coke Series National And Industrial Reference Materials  – Shandong Institute of Metallurgical Science

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China Crms Manufacturers – Coke Series National And Industrial Reference Materials – Shandong Institute of Metallurgical Science

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China Crms Manufacturers – Coke Series National And Industrial Reference Materials – Shandong Institute of Metallurgical Science Detail:

Table 1. Certified Values for GSB 03-2022-2006 (Mass Fraction %)

Number

Elements

TFe

FeO

SiO2

Al2O3

CaO

MgO

S

GSB

03-2022-2006

Certified Values

61.53

0.24

3.43

2.12

0.118

0.109

0.038

Uncertainty

0.10

0.01

0.04

0.05

0.007

0.005

0.002

Number

Elements

P

Mn

Ti

K2O

Na2O

Cu

Ni

GSB

03-2022-2006

Certified Values

0.068

0.276

0.052

0.026

0.034

0.0014

0.0027

Uncertainty

0.002

0.005

0.002

0.003

0.003

0.0002

0.0003.

Number

Elements

Co

As

Pb

Zn

Cr

 

 

GSB

03-2022-2006

Certified Values

0.0009

0.0011

0.0008

0.0020

0.0054

 

 

Uncertainty

0.0001

0.0002

0.0001

0.0003

0.0004

 

 

Table 2. Analysis Methods

Composition

Method

TFe

Titrimetric method after tin (Ⅱ) chloride reduction

Titanium (Ⅲ) chloride reduce potassium dichromate titration method

FeO

Potassium dichromate titration method

Sulfosalicylic acid spectrophotometric method

Potentiometric titration method

SiO2

Perchloric acid dehydration gravimetric method

The silicomolybdic blue spectrophotometric method

ICP-AES

CaO

AAS

ICP-AES

MgO

AAS

ICP-AES

Al2O3

EDTA titrimetric method

ICP-AES

Ti

ICP-AES

Diantipyrylmethane spectrophotometric method

Mn

ICP-AES

AAS 

Potassium periodate spectrophotometric method

P

N-butyl alcohol-chloroform extraction molybdenum blue spectrophotome-tric method

The butyl acetate extraction photometric method

Phosphovanoclonoiybeate molecular absorption spectromrtric method

Bismuth phosphomolybdenum blue photometry

ICP-AES

S

High frequency combustion infrared absorption method

Barium sulfate gravimetric method

Combustion iodometric method

K2O

ICP-AES

AAS

Na2O

ICP-AES

AAS

Cu

ICP-AES

AAS

GFAAS

Ni

AAS

GFAAS

ICP-AES

Co

AAS

GFAAS

ICP-AES

As

Silver diethyldithiocarbamate spectrophotometry

Arseno molybdenum blue spectrophotometric method after the extraction separation

GFAAS

HGAAS

ICP-AES

Pb

GFAAS

AAS

ICP-AES

ICP-MS

Zn

ICP-AES

AAS

Cr

AAS

GFAAS

ICP-AES

The certified reference material is packed in glass bottles with plastic covers. The net weight is 50g each. It is suggested to keep dryness when stored. The certified reference material should be dried at 105℃ for 1 hour before use, then it should be taken out and cooled to room temperature.


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China Crms Manufacturers –  Coke Series National And Industrial Reference Materials  – Shandong Institute of Metallurgical Science detail pictures

China Crms Manufacturers –  Coke Series National And Industrial Reference Materials  – Shandong Institute of Metallurgical Science detail pictures


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